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silver fulminate : ウィキペディア英語版
silver fulminate

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Silver fulminate (AgCNO) is the highly explosive silver salt of fulminic acid.
Silver fulminate is a primary explosive but has limited use as such due to its extreme sensitivity to impact, heat, pressure and electricity. The compound becomes progressively sensitive as it is aggregated, even in small amounts; the touch of a falling feather, the impact of a single water droplet or a small static discharge are all capable of explosively detonating an unconfined pile of silver fulminate no larger than a dime and no heavier than a few milligrams. Aggregation of larger quantities is impossible due to the compound's tendency to self-detonate under its own weight.
Silver fulminate was first prepared in 1800 by Edward Charles Howard in his research project to prepare a large variety of fulminates. Along with mercury fulminate, it is the only fulminate stable enough for commercial use. Detonators using silver fulminate were used to initiate picric acid in 1885, but since have only been used by the Italian navy.〔 The current commercial use has been in producing non-damaging novelty noisemakers as children's toys and tricks.
==Structure==

Silver fulminate occurs in two polymorphic forms, an orthorhombic one and a trigonal one with a rhombohedral lattice. The trigonal polymorph consists of cyclic hexamers, (AgCNO)6.

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